Gallou, Fabrice (2021) Visible Light mediated micellar one-pot Triazole formation. ChemSusChem, 14. pp. 2704-2710. ISSN 1864-564X; 1864-5631

Abstract

The amphiphilic Cu nanoparticles (NPs) stabilized with proline linker of the amphiphile is reported. The NPs was characterized using various spectroscopic techniques like XAS, XPS, cryoTEM and HRTEM analysis. DFT calculations confirm the tertiary amide core of the amphilphile as an active binding site for the Cu NPs. The highly active Cu NPs is employed in visible light mediated photo-initiator free cycloaddition reaction and C-H aminations using parts per million level of catalyst loading. The Cu NPs is easy to synthesize and ound to be highly stable and recyclable. .

Item Type:	Article
Keywords:	micelles
Date Deposited:	10 Aug 2021 00:45
Last Modified:	10 Aug 2021 00:45
URI:	https://oak.novartis.com/id/eprint/45060