Delgado, Pete, Glass, Raoul Julian, Geraci, Gina, Duvadie, Rohit, Majumdar, Dyuti, Robinson, Richard, Elmaarouf, Imran, Mikus, Malte and Tan, Kian (2021) Use of Green Solvents in Metallaphotoredox Cross-Electrophile Coupling Reactions Utilizing a Lipophilic Modified Dual Ir/Ni Catalyst System. Journal of Organic Chemistry, 86 (23). 17428-17436. ISSN 1520-6904

Abstract

Facilitating photoredox coupling reactions in process-friendly green solvents was achieved by the successful application of a dual Ir/Ni catalyst system with enhanced solubility properties. These photochemical reactions (specifically Br–Br sp2–sp3 cross electrophile coupling) are reported in a head to head comparison to the standard di-t-Bu bipyridine ligand Ir/Ni catalyst system. This presentation highlights the benefits of altering the solubility properties of the ligands used in the Ir/Ni dual catalyst.

Item Type:	Article
Keywords:	photoredox green chemistry cross coupling
Date Deposited:	20 Jan 2022 00:45
Last Modified:	20 Jan 2022 00:45
URI:	https://oak.novartis.com/id/eprint/44865