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Catalytic meta-selective C-H functionalization to construct quaternary carbon centres

Press, Neil and Paterson, Andrew and St John-Campbell, Sahra and Mahon, Mary and Frost, Christopher (2015) Catalytic meta-selective C-H functionalization to construct quaternary carbon centres. Chemical Communications, 51 (64). ISSN 1359-73451364-548X

Abstract

A catalytic meta-selective C-H functionalization of 2-phenylpyridines using a range of tertiary halides is described. The protocol is simple to perform and usees commercially available reagents to construct challenging quaternary carbon centres in a regioselective manner. Preliminary studies suggest the C-H functionalization proceeds trhough a radical process directed via a remote sigma activation.

Item Type: Article
Date Deposited: 26 Apr 2016 23:45
Last Modified: 26 Apr 2016 23:45
URI: https://oak.novartis.com/id/eprint/25922

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