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Rhodium-Catalyzed Ketone Alkylation Using Methanol Under Mild Conditions: Formation of Alpha-Branched Products

Healy, Mark and Chan, Louis and Poole, Darren and Shen, Di and Donohoe, Timothy (2014) Rhodium-Catalyzed Ketone Alkylation Using Methanol Under Mild Conditions: Formation of Alpha-Branched Products. Angewandte Chemie (International Ed. in English), 53 (3). pp. 761-765. ISSN 14337851

Abstract

We report our findings into the synthesis of α-branched
ketone products by the alkylation of ketones using methanol. Pleasingly we have found that methanol alkylation could be observed at 65 °C,17 indicating that methanol dehydrogenation can be achieved under these mild oxidative conditions, and this represents a convenient method for the use of methanol as a renewable C1-synthetic building block.

Item Type: Article
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Keywords: Rhodium, Catalysis, Methanol
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Date Deposited: 24 Jun 2016 23:45
Last Modified: 24 Jun 2016 23:45
URI: https://oak.novartis.com/id/eprint/10844

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