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Asymmetric synthesis of the homalium alkaloids (–)-(S,S)-homaline and (–)-(R,R)-hopromine

Stonehouse, Jeff, Davies, Stephen, Lee, James, Roberts, Paul and Thomson, James (2012) Asymmetric synthesis of the homalium alkaloids (–)-(S,S)-homaline and (–)-(R,R)-hopromine. Journal of Organic Chemistry, 77 (16). pp. 7028-7045. ISSN 0022-3263


Efficient asymmetric syntheses of (–)-(S,S)-homaline and (–)-(R,R)-hopromine have been achieved using the
conjugate addition of enantiopure N-3-chloropropyl substituted lithium amides to alpha,beta-unsaturated esters as
the key step.

Item Type: Article
Related URLs:
Additional Information: part of the EPSRC/CASE collaboration between Novartis and the University of Oxford (Prof Steve Davies)
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Date Deposited: 13 Oct 2015 13:14
Last Modified: 13 Oct 2015 13:14


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