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Room Temperature Asymmetric Allylic Trifluoromethylation of Morita Baylis-Hillman Carbonates

Li, Yun and Liang, Fang and Li, Qian and Xu, Yao-Chang and Wang, Quan-Rui and Jiang, Lei (2011) Room Temperature Asymmetric Allylic Trifluoromethylation of Morita Baylis-Hillman Carbonates. Organic Letters, 13 (22). pp. 6082-6085. ISSN 1523-7060

Abstract

(DHQD)2PHAL catalyzed asymmetric allylic trifluoromethylation of Morita-Baylis-Hillman adducts using Rupert-Prakash reagent was reported. This transformation provided the SN2′ trifluoromethylated prodcuts with good yields and excellent enantioselectivities at room temperature. It was also found that the reaction could be accelerated using acetonitrile as co-solvent

Item Type: Article
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Date Deposited: 13 Oct 2015 13:15
Last Modified: 13 Oct 2015 13:15
URI: https://oak.novartis.com/id/eprint/5850

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