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Transition-Metal Free Allylic Fluorination of Acyclic Olefins

McKenna, Jeffrey, Saini, Vaneet, Chaudhary, Nishita, Singh, Kamal Nain and Singh, Harjinder (2022) Transition-Metal Free Allylic Fluorination of Acyclic Olefins. Synthesis. ISSN 1437-210X; 0039-7881


one step allylic fluorination of alkenes is reported which furnishes the products in a
highly regioselective manner via allylic rearrangement. The reaction proceeds
efficiently under mild conditions with the use of trisubstituted alkenes as olefin partner
and Selectfluor as an electrophilic fluorinating agent without the need of any transitionmetal
catalyst or pre-functionalized substrates

Item Type: Article
Date Deposited: 29 Oct 2022 00:45
Last Modified: 29 Oct 2022 00:45


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