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α-Arylation of (Hetero)aryl Ketones in Aqueous Surfactant Media

Gallou, Fabrice (2021) α-Arylation of (Hetero)aryl Ketones in Aqueous Surfactant Media. Green chemistry, 23. pp. 4858-4865.


α-Arylation reactions can be performed in water, enabled by a designer surfactant,under mild conditions and in the absence
of organic co-solvents. A multitude of aryl and heteroaryl ketones are amenable to coupling with functionalized aryl halides.
Use of a lipophilic base that can gain entry to the micellar inner cores mediates enolization. In some cases, palladium loadings
as low as 2500 ppm (0.25 mol %) are sufficient for coupling in a completely recyclable medium, exemplifying chemistry in

Item Type: Article
Date Deposited: 28 Sep 2021 00:45
Last Modified: 28 Sep 2021 00:45


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