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TMS-ent-Bisabolangelone

Riss, Bernard (2017) TMS-ent-Bisabolangelone. Tetrahedron, 73 (23). pp. 3202-3212. ISSN 00404020

Abstract

The absolute configuration of bisabolangelone has been established by an eleven step total synthesis of the corresponding TMS protected antipode starting from R-(+)-pulegone. Comparison of the TMS-derivatives by GC on a chiral column, allowed us to assign the absolute configuration of the synthetic compound and thus of the corresponding natural product.

Item Type: Article
Keywords: Bisabolangelone, Sesquiterpene, Bisabolane, Configuration, Perhydrobenzofuran.
Date Deposited: 30 May 2017 00:45
Last Modified: 30 May 2017 00:45
URI: https://oak.novartis.com/id/eprint/31865

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