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Intermolecular interactions between encapsulated aromatic compounds and the host framework of a Crystalline Sponge

Hayes, Lilian, M. and Press, Neil and Tocher, Derek, A. and Carmalt, Claire, J. (2017) Intermolecular interactions between encapsulated aromatic compounds and the host framework of a Crystalline Sponge. Crystal Growth & Design, 17 (2). pp. 858-863. ISSN 1528-74831528-7505

Abstract

The crystalline sponge [{(ZnI2)3(tris(4-pyridyl)-1,3,5-triazine)2.x(solvent)}n] has been use to produce a range of novel encapsulation compounds with acetophene, trans-cinnamaldehyde, naphthalene, anthracene and benzylcyanide. Using additional data from previously reported encapsulation compounds, three systematic series have been created and analysed to investigate the behaviour of guest molecules within the sponge framework and identify the dominant intermolecular interactions.

Item Type: Article
Keywords: crystalline sponge, encapsulation compounds, pi-pi interactions, CH∙∙∙pi interactions
Date Deposited: 01 Feb 2017 00:45
Last Modified: 01 Feb 2017 00:45
URI: https://oak.novartis.com/id/eprint/31491

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