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Gold Catalysed Redox Synthesis of Imidazo[1,2a]pyridine using Pyridine N-Oxide and Alkynes

Mckenna, Jeff and Talbot, Eric and Richardson, Melodie and Toste, F. Dean (2014) Gold Catalysed Redox Synthesis of Imidazo[1,2a]pyridine using Pyridine N-Oxide and Alkynes. Gold Catalysed Redox Synthesis of Imidazo[1,2a]pyridine using Pyridine N-Oxide and Alkynes, 356. pp. 687-691.

Abstract

A mild, catalytic, atom economical synthesis of imidazo[1,2a]pyridine has been developed: catalytic PicAuCl in the presence of acid produces a range Imidazo[1,2a]pyridines in good yield. This strategy is mild and forseen to be particularly useful installation of stereogenic centers adjacent to the imidazo[1,2a]pyridine ring without loss of e.e.

Item Type: Article
Date Deposited: 13 Oct 2015 13:13
Last Modified: 13 Oct 2015 13:13
URI: https://oak.novartis.com/id/eprint/20267

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